Correction to “Arylazopyrazoles: Azoheteroarene Photoswitches Offering Quantitative Isomerization and Long Thermal Half-Lives

Supporting information Connectivity matters - Ultrafast isomerization dynamics of bisazobenzenes photoswitches

Nuclear Binding and Half-Lives

Nuclear Forces. Protons give the nucleus of an atom a net positive charge. So, why doesn’t the nucleus explode? Nuclear stability is possible because the particles in the nucleus are each tiny magnets, and magnets can be arranged to attract one another. When the particles inside the nucleus have specific locations, the forces from electrical charge can be in balance with the magnetic forces fro...

Correction to “Simple, Chemoselective, Catalytic Olefin Isomerization”

Page 16788 and Supporting Information page SI-4. Entry 13 was inadvertently omitted from Table 1 and S.I. Table 1. This entry suggests mechanistic overlap between our alkene isomerization and hydrogen atom transfer radical polymer-ization, more so than entry 12 alone. The complete S.I. Table 1 is shown below. This is an open access article published under an ACS AuthorChoice License, which perm...

Quantitative podocyte parameters predict human native kidney and allograft half-lives.

BACKGROUND Kidney function decreases with age. A potential mechanistic explanation for kidney and allograft half-life has evolved through the realization that linear reduction in glomerular podocyte density could drive progressive glomerulosclerosis to impact both native kidney and allograft half-lives. METHODS Predictions from podometrics (quantitation of podocyte parameters) were tested usi...

Arylazoindazole Photoswitches: Facile Synthesis and Functionalization via SNAr Substitution

A straightforward synthetic route to arylazoindazoles via nucleophilic aromatic substitution is presented. Upon deprotonation of the NH group, a C6F5-substituted formazan undergoes facile cyclization as a result of intermolecular nucleophilic substitution (SNAr). This new class of azo photoswitches containing an indazole five-membered heterocycle shows photochemical isomerization with high fati...